- Introduction of 2,2,2-trichloroethoxycarbonyl (Troc) group at amino . . .
The 2,2,2-trichloroethoxycarbonyl (Troc) group is one of the most widely used carbamate protection for the amino groups of 2-amino sugars and neuraminic acid (1, 2)
- Widely Applicable Deprotection Method of 2,2,2-Trichloroethoxycarbonyl . . .
The N -Troc (2,2,2-trichloroethoxycarbonyl) groups in glucosamine and muramic acid derivatives were removed by treatment with tetrabutylammonium fluoride (TBAF) under mild conditions
- 2,2,2-Trichloroethoxycarbonylation (Troc) Reagents [Protecting Reagents . . .
2,2,2-Trichloroethoxycarbonyl (Troc) group is used as a protecting group for hydroxy groups and amino groups Troc group is generally deprotected by the treatment with zinc powder or by electrolysis
- Highly Chemoselective Deprotection of the 2,2,2-Trichloroethoxycarbonyl . . .
Nonreducing, pH-neutral conditions for the selective cleavage of the 2,2,2-trichloroethoxycarbonyl (Troc) protecting group are reported
- Glycosylation with N -Troc-protected glycosyl donors
N -Troc-protected (Troc = 2,2,2-trichloroethoxycarbonyl) glucosamine and galactosamine glycosyl donors (1- O -acetyl sugar, bromo sugar, and thioglycoside) were compared with the corresponding N -Phth-protected derivatives in glycosylations of 2- (trimethylsilyl)ethanol, 2-bromoethanol, methyl 3-mercaptopropionate, N -Fmoc-protected serine, and
- Methyl 6-O-[3-O,4-O,6-O-triacetyl-2-(2,2,2-trichloroethoxycarbonylamino . . .
Chemical Substance "Methyl 6-O-[3-O,4-O,6-O-triacetyl-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-β-D-glucopyranosyl]-4-O-(2-O,3-O,4-O,6-O-tetraacetyl-β-D-galactopyranosyl)-3-O-benzyl-2-O-[4-[5-[26-[4-(1,1,3,3-tetramethylbutyl)phenoxy]-3,6,9,12,15,18,21,24-octaoxahexacosane-1-yloxy]-1,5-dioxopentylamino]benzyl]-β-D-glucopyranoside
- Cas 151909-93-2,1,3,4,6-Tetra-O-acetyl-2-(2,2,2 . . . - LookChem
Lookchem Provide Cas No 151909-93-2 Basic information: Properties,Safety Data,Sds and Other Datebase We also Provide Trading Suppliers Manufacture for 151909-93-2 1,3,4,6-Tetra-O-acetyl-2- (2,2,2-trichloroethoxycarbonylamino)-2-deoxy-α β-D-galactopyranose
- Conversion of N-2,2,2-Trichloroethoxycarbonyl-Protected 2 . . .
N-2,2,2-Trichloroethoxycarbonyl (Troc)-protected glycosamine derivatives are versatile glycosyl donors in oligosaccharide syntheses The Troc protecting group can easily be introduced via its acid chloride; it is stable under acidic conditions but is base labile It can be selectively cleaved under reductive conditions
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